macadamia oil saponification and lye calculator
Saponifying one gram of macadamia oil takes about 0.139 g of sodium hydroxide, or 0.1950 g of potassium hydroxide for liquid soap. Superfatting leaves a deliberate excess of oil so no free lye survives.
- Water
- 165.0
- Lye at 100% purity
- 66.03
- Lye with no superfat
- 69.50
- Lye solution concentration Most recipes run 28 to 33%. Above 35% the solution is aggressive and traces very fast.
- 28.58 %
- Water to lye ratio
- 2.499
- Total batch weight
- 731
- Approximate 110 g bars
- 6.6
- Oil left unsaponified
- 25.0
Show the working
- Weight of macadamia oil = 500
- Superfat = 5
- Water as a share of oil = 33
- Lye = 1
- Lye purity = 100
- sap = 0.139 = 0.139
- Lye with no superfat = 500 * 0.139 * 1 = 69.5
- Lye at 100% purity = 69.5 * (1 - 5/100) = 66.025
- Lye to weigh out = 66.025 / (100/100) = 66.025
- Water = 500 * 33/100 = 165
- Lye solution concentration = (165 + 66.025) > 0 ? 66.025 / (165 + 66.025) * 100 : 0 = 28.5792
- Water to lye ratio = 66.025 > 0 ? 165 / 66.025 : 0 = 2.499 05
- Total batch weight = 500 + 165 + 66.025 = 731.025
- Approximate 110 g bars = 731.025 / 110 = 6.645 68
- Oil left unsaponified = 500 * 5/100 = 25
Values are shown to six significant figures here; the arithmetic itself runs on exact fractions and is only rounded where a number is printed.
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The formula
- lye = oil weight x saponification value x (1 - superfat)
- potassium hydroxide needs 1.403 times the sodium hydroxide weight, the ratio of their molar masses
- lye concentration = lye / (lye + water)
Sodium hydroxide is caustic and generates heat on contact with water. Always add lye to water, never the reverse, and wear eye protection and gloves. Run any recipe through a second calculator before making it.
Saponification values are measured properties of a natural product and vary by a few percent between batches, pressings and suppliers. A 5% superfat covers that variation as well as leaving the soap gentle.
Potassium hydroxide is often sold at 90% purity. Set the purity field accordingly or the soap will be lye-heavy.
Frequently asked
What is the SAP value of macadamia oil?
0.139 g of sodium hydroxide per gram of oil, or 0.1950 g of potassium hydroxide.
Why superfat?
Superfatting leaves a small excess of oil so that natural variation in the saponification value can never leave free lye in the finished bar.
Where the numbers come from
- Saponification values are the standard published figures for this oil; treat them as approximate.
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